3d Transition Metals

Titanium, Chromium, and Manganese

Titanium, chromium and manganese are 3d transition metals notably used to add corrosion-resistance, durability, and lightness to steel.

Learning Objectives

Recall the beneficial physical characteristics that titanium, chromium, and manganese impart when doped into steel.

Key Takeaways

Key Points

  • The two most useful properties of titanium include its resistance to corrosion and its high strength-to-weight ratio.
  • Chromium metal is highly valuable due to its high corrosion resistance and hardness.
  • Manganese is a metal with important industrial metal alloy uses, particularly in stainless steels.

Key Terms

  • stainless steel: An alloy of iron and chromium that resists corrosion.
  • titanium: A strong, corrosion-resistant transition metal with the atomic number 22.

Titanium, chromium, and manganese are transition metals that are used in many iron alloys to produce corrosion-resistant, durable, and lightweight steel.

Titanium

Titanium is a strong, lustrous transition metal. It has a low density, is corrosion-resistant, and has a silver color. Titanium was discovered in Cornwall, Great Britain, in 1791, by William Gregor. It was named by Martin Heinrich Klaproth, in honor of the Titans of Greek mythology.

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A titanium bar: Titanium is one of the least dense, strong, and corrosion-resistant elements. It has many applications, especially in alloys with other elements such as iron. Titanium is commonly used in airplanes, golf clubs, and other objects that must be strong but lightweight.

Titanium can be alloyed with iron, aluminum, vanadium, molybdenum, and several other elements to produce strong, lightweight alloys that are used in a variety of industries, including:

  • aerospace construction (jet engines, missiles, and spacecraft)
  • military development
  • industrial process (chemicals and petro-chemicals, desalination plants, pulp, and paper)
  • the automotive industry
  • the agriculture and food industry
  • medical prostheses
  • orthopedic implants
  • dental and endodontic instruments
  • dental implants
  • sporting goods
  • jewelry
  • mobile phones

Titanium metal has two very important and useful properties: it is resistant to corrosion and it has the highest strength-to-weight ratio of any metal. In its unalloyed condition, titanium is as strong as some steels, but 45% lighter.

Chromium

Chromium is a steely-gray, lustrous, hard metal that takes a high polish and has a high melting point. It is odorless, tasteless, and malleable. The name of the element is derived from the Greek word “chrōma” (χ), meaning color, because many of its compounds are intensely colored.

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Chromium: Chromium, like titanium and vanadium before it, is extremely resistant to corrosion, and is indeed one of the main components of stainless steel. Chromium also has many colorful compounds and is very commonly used in pigments, such as chrome green.

Chromium oxide was used by the Chinese in the Qin dynasty over 2,000 years ago to coat metal weapons. Weapons coated with chromium oxide were found with the Terracotta Army. Chromium was discovered as an element after 1761, when it was found in the red crystalline mineral, crocoite (lead(II) chromate). It was initially used as a pigment.

Louis Nicolas Vauquelin was the first to isolate the chromium metal from this crocoite mineral, in 1797. Following this first discovery, small amounts of native (free) chromium metal have been discovered in rare minerals, but these are not used commercially. Nearly all of the chromium that is commercially extracted is done so from the only commercially viable ore, chromite, which is also known as iron chromium oxide (FeCr2O4). Chromite is also the chief source for the chromium that is used in pigments.

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Crocoite: Crocoite is a mineral formed from lead chromate (PbCrO4), a chromium compound.

Chromium metal has proven to be highly valuable due to its high corrosion resistance and hardness, particularly when steel is combined with metallic chromium to form stainless steel. Stainless steel is highly resistant to corrosion and discoloration. This application, along with chrome plating (electroplating with chromium), currently comprises 85% of the commercial use for the element. Other applications of chromium compounds account for the remaining 15%.

Manganese

Manganese is found as a free element in nature (often in combination with iron), and is also found in many minerals. It is a metal with important industrial uses, particularly in stainless steels.

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Manganese: Manganese, like chromium before it, is an important component in stainless steel, preventing the iron from rusting. Manganese is often used in pigments, again like chromium. Manganese is also poisonous; if enough is inhaled, it can cause irreversible neurological damage.

Historically, manganese was named for various black minerals (such as pyrolusite) that were discovered in the same region of Magnesia in Greece. By the mid-18th century, Swedish chemist Carl Wilhelm Scheele had used pyrolusite to produce chlorine. Scheele and others were aware that pyrolusite (now known as manganese dioxide) contained a new element, but they were not able to isolate it. Johan Gottlieb Gahn was the first to isolate an impure sample of manganese metal in 1774, by reducing the dioxide with carbon.

Manganese phosphating is used as a treatment for rust and corrosion on steel. Depending on their oxidation state, manganese ions have various colors and are used industrially as pigments. Manganese dioxide is used as the cathode (electron acceptor) material in zinc-carbon and alkaline batteries.

In biology, manganese(II) ions function as cofactors for a large variety of enzymes with many functions. Manganese enzymes are particularly essential in the detoxification of superoxide free radicals in organisms that must deal with elemental oxygen. Manganese also functions in the oxygen-evolving complex of photosynthetic plants. The element is a required trace mineral for all known living organisms. If inhaled in large amounts, manganese can cause a poisonous syndrome in mammals, with neurological damage that is sometimes irreversible.

Iron, Cobalt, Copper, Nickel, and Zinc

Cobalt, nickel, copper, and zinc are 3d orbital transition metals with a variety of properties.

Learning Objectives

Recall the characteristics of cobalt, copper, nickel and zinc in their elemental states and when combined in alloys.

Key Takeaways

Key Points

  • Copper is the most heavily used coinage metal due to its electrical properties, its abundance (contrasted to silver and gold), and the attractiveness of its alloys — brass and bronze.
  • Zinc is used in alloys with copper to create a harder metal known as brass.
  • In galvanization, zinc coats iron by oxidizing to form a protective layer of zinc oxide (ZnO) that protects the iron from rust.
  • Cobalt and nickel are trace elements with properties similar to iron.

Key Terms

  • copper: A reddish-brown, malleable, ductile metallic element with high electrical and thermal conductivity. Its symbol is Cu and its atomic number is 29.
  • brass: A metallic alloy of copper and zinc used in many industrial and plumbing applications.
  • bronze: A natural or man-made alloy of copper, usually with tin, but also with one or more other metals.

Copper

Copper is a member of a family of metals known as the “coinage metals,” which includes copper, silver, gold, and roentgenium. Because of their softness, coinage metals are easily fashioned into coins. Their comparative rarity and attractiveness, along with their resistance to corrosion, make them compact stores of wealth. However, pure copper is too soft to have structural value, but copper alloys with zinc and tin to form harder brasses and bronzes. Brass and bronze were essential components of the earliest metal tools.

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Copper Pipes: Copper is heavily used due in many areas, including copper piping.

Copper is the most heavily used of the coinage metals due to its electrical properties, its abundance (compared to silver and gold), and the properties of its brass and bronze alloys. Until aluminum became commonplace, copper was second only to iron in production among the metals. Copper is easy to identify due to its reddish color.

Copper oxidizes—with some difficulty—to the +1 state in halides and an oxide, and to the +2 state in salts such as copper sulfate CuSO4. Soluble copper compounds are easily identified by their distinctive blue-green color.

Zinc

A zinc coin: Zinc is an essential trace element for living things. It has some germicidal properties and it is toxic in large quantities. Zinc pennies should never be swallowed.

The zinc family consists of zinc, cadmium, mercury, and copernicum. Zinc and cadmium are soft metals that easily oxidize to the +2 oxidation state. Neither of these two metals appears uncombined in nature. Zinc is used in alloys with copper to create a harder metal known as brass. In galvanization, zinc coats iron by oxidizing to form a protective layer of zinc oxide (ZnO) that protects the iron from oxidation. Zinc oxide is much safer than lead oxide, and it is often used in white paint. Since 1982, zinc has been the main metal used in American pennies. It is now used in new organ pipes.

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Cobalt: Like nickel, cobalt in the Earth’s crust is found only in chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal.

Zinc is an essential trace element for living things and has some germicidal properties, but can be toxic in large quantities. Zinc pennies should never be swallowed.

Iron, Cobalt, and Nickel

Iron, cobalt, and nickel are fairly good reducing agents, so they rarely appear uncombined in nature. Iron is one of the most common elements in the universe. Uncombined iron, cobalt, and nickel can be found in meteors.

The earth itself has a hot, dense core made largely of iron and nickel. At the temperatures characteristic of the Earth’s core, iron and nickel form a giant natural magnet which creates the Earth’s magnetic field. This magnetic field blocks dangerous radiation that would kill life on the Earth.