- Describe the deviation from the octet rule by free radicals
- While the majority of compounds formed from atoms below atomic number 20 follow the octet rule, there are many examples of compounds that do not.
- Having an odd number of electrons in a molecule guarantees that it does not follow the octet rule, because the rule requires eight electrons (or two for hydrogen) around each atom.
- The most commonly encountered stable species that exist with an odd number of electrons are nitrogen oxides, such as nitric oxide (NO) and nitrogen dioxide (NO2), both of which are free radicals and disobey the octet rule.
- free radicalAny molecule, ion, or atom with one or more unpaired electrons. They vary in reactivity and stability from highly reactive, occurring as transient (short-lived) species, to metastable.
- metastableOf or pertaining to a physical or chemical state that is relatively long-lived, but may decay to a lower energy state when perturbed.
- octet ruleAtoms lose, gain, or share electrons in order to have a full valence shell of eight electrons. Hydrogen is an exception because it can hold a maximum of two electrons in its valence level.
Some elements, most notably nitrogen, can form compounds that do not obey the octet rule. One class of such compounds are those that have an odd number of electrons. As the octet rule requires eight electrons around each atom, a molecule with an odd number of electrons must disobey the octet rule. Molecules with unpaired electrons are termed ‘free radicals.’ While typically highly unstable, and therefore highly reactive, some free radicals exhibit stability of days, months, or even years. These latter compounds are said to be ‘metastable,’ meaning they will decompose or react if given enough time, but are stable enough for a considerable amount of time, from days to even years, when subjected to only minor disturbances.
Examples of Free Radical Molecules
Recall that the
of a molecule must depict the total number of
from all the atoms which are bonded together.
Nitric oxide has the formula NO. The total number of valence electrons is 5+6=11. Therefore, no matter how electrons are shared between the nitrogen and oxygen atoms, there is no way for nitrogen to have an octet. It will have seven electrons, assuming that the oxygen atom does satisfy the octet.
Nitric oxide is a by-product of combustion reactions that occur in engines, like those in automobile engines and fossil fuel power plants. It is also produced naturally during the electrical discharge of lightning during thunderstorms.
Nitrogen dioxide is the chemical compound with the formula NO2. Again, nitrogen dioxide does not follow the octet rule for one of its atoms, namely nitrogen. The total number of valence electrons is 5+2(6)=17. There is persistent radical character on nitrogen because it has an unpaired electron. The two oxygen atoms in this molecule follow the octet rule.
Nitrogen dioxide is an intermediate in the industrial synthesis of nitric acid, millions of tons of which is produced each year. This reddish-brown toxic gas has a characteristic sharp, biting odor and is a prominent air pollutant.
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