- Identify the general reactions of alkanes
- Alkanes are stable compounds and are generally unreactive.
- The most important application of alkanes is in oxidation reactions; they are used in internal combustion engines as fuel.
- Applying heat and a catalyst can crack larger, more complex alkanes and produce smaller, more useful alkanes and alkenes.
- crackingThe thermal decomposition of a substance, especially that of crude petroleum, in order to produce petrol/gasoline.
- radicalA group of atoms joined by covalent bonds that are characterized by a free, unpaired electron that imparts their reactivity.
- alkaneAny of the saturated hydrocarbons (including methane, ethane, and compounds with long carbon chain known as paraffins, etc.) that have a chemical formula of the form CnH2n+2.
In comparison to alkenes and alkynes, alkanes are relatively unreactive due to the absence of a weaker pi bond in their carbon skeletons. However, there are a few classes of reactions that are commonly performed with alkanes.
The most important reaction that alkanes undergo is combustion. Smaller, linear alkanes generally oxidize more readily than larger, more branched molecules. Alkanes can be burned in the presence of oxygen to produce carbon dioxide, water, and energy; in situations with limited oxygen, the products are carbon monoxide, water, and energy. For this reason, alkanes are frequently used as fuel sources. The combustion of methane is shown:
[latex]CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O +\ energy[/latex]
With the addition of a halogen gas and energy, alkanes can be halogenated with the reactivity of the halogens proceeding in the following order: Cl2>Br2>I2.
In this reaction, UV light or heat initiates a chain reaction, cleaving the covalent bond between the two atoms of a diatomic halogen. The halogen radicals can then abstract protons from the alkanes, which can then combine or react to form more radicals. Alkanes can be halogenated at a number of sites, and this reaction typically yields a mixture of halogenated products.
The complex alkanes with high molecular weights that are found in crude oil are frequently broken into smaller, more useful alkanes by thermal cracking; alkenes and hydrogen gas are also produced by using this method. Thermal cracking is typically performed at high temperatures, and often in the presence of a catalyst. A mixture of products results, and these alkanes and alkenes can be separated by fractional distillation.
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