{"id":134,"date":"2018-03-19T15:47:02","date_gmt":"2018-03-19T15:47:02","guid":{"rendered":"https:\/\/courses.lumenlearning.com\/suny-orgbiochemistry\/chapter\/the-elements\/"},"modified":"2018-07-31T18:27:06","modified_gmt":"2018-07-31T18:27:06","slug":"the-elements","status":"publish","type":"chapter","link":"https:\/\/courses.lumenlearning.com\/suny-monroecc-orgbiochemistry\/chapter\/the-elements\/","title":{"raw":"2.1 The Elements","rendered":"2.1 The Elements"},"content":{"raw":"
\r\n
\r\n
\r\n
\r\n

Learning Objectives<\/h3>\r\n
    \r\n \t
  1. Define a chemical element and give examples of the abundance of different elements.<\/li>\r\n \t
  2. Represent a chemical element with a chemical symbol.<\/li>\r\n<\/ol>\r\n<\/div>\r\n<\/div>\r\n

    An element, as defined in Chapter 1 \"Chemistry, Matter, and Measurement\"<\/a>, is a substance that cannot be broken down into simpler chemical substances. There are about 90 naturally occurring elements known on Earth. Using technology, scientists have been able to create nearly 30 additional elements that do not occur in nature. Today, chemistry recognizes 118 elements\u2014some of which were created an atom at a time by nuclear reactions.<\/p>\r\n\r\n

    \r\n

    Abundance of Elements: Throughout the universe,\u00a0 on Earth and in the Human Body<\/h2>\r\n

    The elements vary widely in abundance. In the universe as a whole, the most common element is hydrogen (about 90% of atoms), followed by helium (most of the remaining 10%). All other elements added together make up less than 1% of the universe.<\/p>\r\n

    On the planet Earth, however, the situation is rather different. Oxygen makes up 46.1% of the mass of Earth\u2019s crust (the relatively thin layer of rock forming Earth\u2019s surface), mostly in combination with other elements, while silicon makes up 28.5%. Hydrogen, the most abundant element in the universe, makes up only 0.14% of Earth\u2019s crust. Table 2.1 \"Elemental Composition of Earth\"<\/a> lists the relative abundances of elements on Earth as a whole and in Earth\u2019s crust. Table 2.2 \"Elemental Composition of a Human Body\"<\/a> lists the relative abundances of elements in the human body. If you compare Table 2.1 \"Elemental Composition of Earth\"<\/a> and Table 2.2 \"Elemental Composition of a Human Body\"<\/a>, you will find disparities between the percentage of each element in the human body and on Earth. Oxygen has the highest percentage in both cases, but carbon, the element with the second highest percentage in the body, is relatively rare on Earth and does not even appear as a separate entry in Table 2.1 \"Elemental Composition of Earth\"<\/a>; carbon is part of the 0.174% representing \u201cother\u201d elements. How does the human body concentrate so many apparently rare elements?<\/p>\r\n\r\n

    \r\n
    Table 2.1<\/span> Elemental Composition of Earth<\/em><\/strong><\/h5>\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n
    Earth\u2019s Crust<\/th>\r\nEarth (overall)<\/th>\r\n<\/tr>\r\n
    Element<\/th>\r\nPercentage<\/th>\r\nElement<\/th>\r\nPercentage<\/th>\r\n<\/tr>\r\n<\/thead>\r\n
    oxygen<\/td>\r\n46.1<\/td>\r\niron<\/td>\r\n34.6<\/td>\r\n<\/tr>\r\n
    silicon<\/td>\r\n28.2<\/td>\r\noxygen<\/td>\r\n29.5<\/td>\r\n<\/tr>\r\n
    aluminum<\/td>\r\n8.23<\/td>\r\nsilicon<\/td>\r\n15.2<\/td>\r\n<\/tr>\r\n
    iron<\/td>\r\n5.53<\/td>\r\nmagnesium<\/td>\r\n12.7<\/td>\r\n<\/tr>\r\n
    calcium<\/td>\r\n4.15<\/td>\r\nnickel<\/td>\r\n2.4<\/td>\r\n<\/tr>\r\n
    sodium<\/td>\r\n2.36<\/td>\r\nsulfur<\/td>\r\n1.9<\/td>\r\n<\/tr>\r\n
    magnesium<\/td>\r\n2.33<\/td>\r\nall others<\/td>\r\n3.7<\/td>\r\n<\/tr>\r\n
    potassium<\/td>\r\n2.09<\/td>\r\n<\/td>\r\n<\/td>\r\n<\/tr>\r\n
    titanium<\/td>\r\n0.565<\/td>\r\n<\/td>\r\n<\/td>\r\n<\/tr>\r\n
    hydrogen<\/td>\r\n0.14<\/td>\r\n<\/td>\r\n<\/td>\r\n<\/tr>\r\n
    phosphorus<\/td>\r\n0.105<\/td>\r\n<\/td>\r\n<\/td>\r\n<\/tr>\r\n
    all others<\/td>\r\n0.174<\/td>\r\n<\/td>\r\n<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n
    \r\n

    Source: D. R. Lide, ed. CRC Handbook of Chemistry and Physics<\/em>, 89th ed. (Boca Raton, FL: CRC Press, 2008\u20139), 14\u201317.<\/p>\r\n\r\n<\/div>\r\n<\/div>\r\n

    \r\n
    Table 2.2<\/span> Elemental Composition of a Human Body<\/em><\/strong><\/h5>\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n
    Element<\/th>\r\nPercentage by Mass<\/th>\r\n<\/tr>\r\n<\/thead>\r\n
    oxygen<\/td>\r\n61<\/td>\r\n<\/tr>\r\n
    carbon<\/td>\r\n23<\/td>\r\n<\/tr>\r\n
    hydrogen<\/td>\r\n10<\/td>\r\n<\/tr>\r\n
    nitrogen<\/td>\r\n2.6<\/td>\r\n<\/tr>\r\n
    calcium<\/td>\r\n1.4<\/td>\r\n<\/tr>\r\n
    phosphorus<\/td>\r\n1.1<\/td>\r\n<\/tr>\r\n
    sulfur<\/td>\r\n0.20<\/td>\r\n<\/tr>\r\n
    potassium<\/td>\r\n0.20<\/td>\r\n<\/tr>\r\n
    sodium<\/td>\r\n0.14<\/td>\r\n<\/tr>\r\n
    chlorine<\/td>\r\n0.12<\/td>\r\n<\/tr>\r\n
    magnesium<\/td>\r\n0.027<\/td>\r\n<\/tr>\r\n
    silicon<\/td>\r\n0.026<\/td>\r\n<\/tr>\r\n
    iron<\/td>\r\n0.006<\/td>\r\n<\/tr>\r\n
    fluorine<\/td>\r\n0.0037<\/td>\r\n<\/tr>\r\n
    zinc<\/td>\r\n0.0033<\/td>\r\n<\/tr>\r\n
    all others<\/td>\r\n0.174<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n
    \r\n

    Source: D. R. Lide, ed. CRC Handbook of Chemistry and Physics, 89th ed. (Boca Raton, FL: CRC Press, 2008\u20139), 7\u201324.<\/em><\/p>\r\n\r\n<\/div>\r\n<\/div>\r\n

    The relative amounts of elements in the body have less to do with their abundances on Earth than with their availability in a form we can assimilate. We obtain oxygen from the air we breathe and the water we drink. We also obtain hydrogen from water. On the other hand, although carbon is present in the atmosphere as carbon dioxide, and about 80% of the atmosphere is nitrogen, we obtain those two elements from the food we eat, not the air we breathe.<\/p>\r\n\r\n

    \r\n
    \r\n
    \r\n
    \r\n

    Looking Closer: Phosphorus, the Chemical Bottleneck<\/h3>\r\n

    There is an element that we need more of in our bodies than is proportionately present in Earth\u2019s crust, and this<\/em> element is not easily accessible. Phosphorus makes up 1.1% of the human body but only 0.105% of Earth\u2019s crust. We need phosphorus for our bones and teeth, and it is a crucial component of all living cells. Unlike carbon, which can be obtained from carbon dioxide, there is no phosphorus compound present in our surroundings that can serve as a convenient source. Phosphorus, then, is nature\u2019s bottleneck. Its availability limits the amount of life our planet can sustain.<\/p>\r\n

    We obtain phosphorus through our diets; most protein-rich foods are also phosphorous-rich. \u00a0 However, plants must absorb it from the environment. When phosphorus-containing detergents were introduced in the 1950s, wastewater from normal household activities greatly increased the amount of phosphorus available to algae and other plant life. Lakes receiving this wastewater experienced sudden increases in growth of algae. When the algae died, concentrations of bacteria that ate the dead algae increased. Because of the large bacterial concentrations, the oxygen content of the water dropped, causing fish to die in large numbers. This process, called eutrophication<\/em>, is considered a negative environmental impact.<\/p>\r\n

    Today, many detergents are made without phosphorus so the detrimental effects of eutrophication are minimized. You may even see statements to that effect on detergent boxes. It can be sobering to realize how much impact a single element can have on life\u2014or the ease with which human activity can affect the environment.<\/p>\r\n\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n

    Names and Symbols<\/h3>\r\n<\/div>\r\n<\/div>\r\n
    \r\n

    Each element has a name. Some of these names date from antiquity, while others are quite new. Today, the names for new elements are proposed by their discoverers but must be approved by the International Union of Pure and Applied Chemistry, an international organization that makes recommendations concerning all kinds of chemical terminology.<\/p>\r\n

    The names of the elements can be cumbersome to write in full, especially when combined to form the names of compounds. Therefore, each element name is abbreviated as a one- or two-letter chemical.<\/span><\/strong><\/span>\u00a0By convention, the first letter of a chemical symbol is a capital letter, while the second letter (if there is one) is a lowercase letter. The first letter of the symbol is usually the first letter of the element\u2019s name, while the second letter is some other letter from the name. Some elements have symbols that derive from earlier, mostly Latin names, so the symbols may not contain any letters from the English name. Table 2.3 \"Element Names and Symbols\"<\/a> lists the names and symbols of some of the most familiar elements.<\/p>\r\n\r\n

    \r\n
    Table 2.3<\/span> Element Names and Symbols<\/em><\/strong><\/h5>\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n
    aluminum<\/td>\r\nAl<\/td>\r\nmagnesium<\/td>\r\nMg<\/td>\r\n<\/tr>\r\n
    argon<\/td>\r\nAr<\/td>\r\nmanganese<\/td>\r\nMn<\/td>\r\n<\/tr>\r\n
    arsenic<\/td>\r\nAs<\/td>\r\nmercury<\/td>\r\nHg*<\/td>\r\n<\/tr>\r\n
    barium<\/td>\r\nBa<\/td>\r\nneon<\/td>\r\nNe<\/td>\r\n<\/tr>\r\n
    bismuth<\/td>\r\nBi<\/td>\r\nnickel<\/td>\r\nNi<\/td>\r\n<\/tr>\r\n
    boron<\/td>\r\nB<\/td>\r\nnitrogen<\/td>\r\nN<\/td>\r\n<\/tr>\r\n
    bromine<\/td>\r\nBr<\/td>\r\noxygen<\/td>\r\nO<\/td>\r\n<\/tr>\r\n
    calcium<\/td>\r\nCa<\/td>\r\nphosphorus<\/td>\r\nP<\/td>\r\n<\/tr>\r\n
    carbon<\/td>\r\nC<\/td>\r\nplatinum<\/td>\r\nPt<\/td>\r\n<\/tr>\r\n
    chlorine<\/td>\r\nCl<\/td>\r\npotassium<\/td>\r\nK*<\/td>\r\n<\/tr>\r\n
    chromium<\/td>\r\nCr<\/td>\r\nsilicon<\/td>\r\nSi<\/td>\r\n<\/tr>\r\n
    copper<\/td>\r\nCu*<\/td>\r\nsilver<\/td>\r\nAg*<\/td>\r\n<\/tr>\r\n
    fluorine<\/td>\r\nF<\/td>\r\nsodium<\/td>\r\nNa*<\/td>\r\n<\/tr>\r\n
    gold<\/td>\r\nAu*<\/td>\r\nstrontium<\/td>\r\nSr<\/td>\r\n<\/tr>\r\n
    helium<\/td>\r\nHe<\/td>\r\nsulfur<\/td>\r\nS<\/td>\r\n<\/tr>\r\n
    hydrogen<\/td>\r\nH<\/td>\r\ntin<\/td>\r\nSn*<\/td>\r\n<\/tr>\r\n
    iron<\/td>\r\nFe<\/td>\r\ntungsten<\/td>\r\nW\u2020<\/sup><\/td>\r\n<\/tr>\r\n
    iodine<\/td>\r\nI<\/td>\r\nuranium<\/td>\r\nU<\/td>\r\n<\/tr>\r\n
    lead<\/td>\r\nPb*<\/td>\r\nzinc<\/td>\r\nZn<\/td>\r\n<\/tr>\r\n
    lithium<\/td>\r\nLi<\/td>\r\nzirconium<\/td>\r\nZr<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n
    *The symbol comes from the Latin name of element.<\/th>\r\n<\/tr>\r\n
    \u2020<\/sup>The symbol for tungsten comes from its German name\u2014wolfram<\/em>.<\/th>\r\n<\/tr>\r\n<\/tfoot>\r\n<\/table>\r\n<\/div>\r\n
    \r\n
    \r\n

    Note<\/h3>\r\n

    Element names in languages other than English are often close to their Latin names. For example, gold is oro<\/em> in Spanish and or<\/em> in French (close to the Latin aurum<\/em>), tin is esta\u00f1o<\/em> in Spanish (compare to stannum<\/em>), lead is plomo<\/em> in Spanish and plomb<\/em> in French (compare to plumbum<\/em>), silver is argent<\/em> in French (compare to argentum<\/em>), and iron is fer<\/em> in French and hierro<\/em> in Spanish (compare to ferrum<\/em>). The closeness is even more apparent in pronunciation than in spelling.<\/p>\r\n\r\n<\/div>\r\n<\/div>\r\n

    \r\n

    Example 1<\/h3>\r\n

    Write the chemical symbol for each element without consulting Table 2.3 \"Element Names and Symbols\"<\/a>.<\/p>\r\n\r\n

      \r\n \t
    1. bromine<\/li>\r\n \t
    2. boron<\/li>\r\n \t
    3. carbon<\/li>\r\n \t
    4. calcium<\/li>\r\n \t
    5. gold<\/li>\r\n<\/ol>\r\n

      Solution<\/p>\r\n[reveal-answer q=\"657335\"]Show Answer[\/reveal-answer]\r\n[hidden-answer a=\"657335\"]\r\n

        \r\n \t
      1. Br<\/li>\r\n \t
      2. B<\/li>\r\n \t
      3. C<\/li>\r\n \t
      4. Ca<\/li>\r\n \t
      5. Au[\/hidden-answer]<\/li>\r\n<\/ol>\r\n<\/div>\r\n
        \r\n
        \r\n

        Skill-Building Exercise<\/h3>\r\n

        Write the chemical symbol for each element without consulting\u00a0Table 2.3 \"Element Names and Symbols\"<\/a>.<\/p>\r\n\r\n

          \r\n \t
        1. \r\n
          \r\n

          manganese<\/p>\r\n\r\n<\/div><\/li>\r\n \t

        2. \r\n
          \r\n

          magnesium<\/p>\r\n\r\n<\/div><\/li>\r\n \t

        3. \r\n
          \r\n

          neon<\/p>\r\n\r\n<\/div><\/li>\r\n \t

        4. \r\n
          \r\n

          nitrogen<\/p>\r\n\r\n<\/div><\/li>\r\n \t

        5. \r\n
          \r\n

          silver<\/p>\r\n\r\n<\/div><\/li>\r\n<\/ol>\r\n<\/div>\r\n<\/div>\r\n

          \r\n

          Example 2<\/h3>\r\n

          What element is represented by each chemical symbol?<\/p>\r\n\r\n

            \r\n \t
          1. Na<\/li>\r\n \t
          2. Hg<\/li>\r\n \t
          3. P<\/li>\r\n \t
          4. K<\/li>\r\n \t
          5. I<\/li>\r\n<\/ol>\r\n

            Solution<\/p>\r\n[reveal-answer q=\"294485\"]Show Answer[\/reveal-answer]\r\n[hidden-answer a=\"294485\"]\r\n

              \r\n \t
            1. sodium<\/li>\r\n \t
            2. mercury<\/li>\r\n \t
            3. phosphorus<\/li>\r\n \t
            4. potassium<\/li>\r\n \t
            5. iodine[\/hidden-answer]<\/li>\r\n<\/ol>\r\n<\/div>\r\n
              \r\n
              \r\n

              Skill-Building Exercise<\/h3>\r\n

              What element is represented by each chemical symbol?<\/p>\r\n\r\n

                \r\n \t
              1. \r\n
                \r\n

                Pb<\/p>\r\n\r\n<\/div><\/li>\r\n \t

              2. \r\n
                \r\n

                Sn<\/p>\r\n\r\n<\/div><\/li>\r\n \t

              3. \r\n
                \r\n

                U<\/p>\r\n\r\n<\/div><\/li>\r\n \t

              4. \r\n
                \r\n

                O<\/p>\r\n\r\n<\/div><\/li>\r\n \t

              5. \r\n
                \r\n

                F<\/p>\r\n\r\n<\/div><\/li>\r\n<\/ol>\r\n<\/div>\r\n<\/div>\r\n

                \r\n
                \r\n
                \r\n

                Concept Review Exercises<\/h3>\r\n
                  \r\n \t
                1. \r\n
                  \r\n

                  What is an element?<\/p>\r\n\r\n<\/div><\/li>\r\n \t

                2. \r\n
                  \r\n

                  Give some examples of how the abundance of elements varies.<\/p>\r\n\r\n<\/div><\/li>\r\n \t

                3. \r\n
                  \r\n

                  Why are chemical symbols so useful? What is the source of the letter(s) for a chemical symbol?<\/p>\r\n\r\n<\/div><\/li>\r\n<\/ol>\r\n<\/div>\r\n

                  \r\n

                  Answers<\/h3>\r\n<\/div>\r\n[reveal-answer q=\"299465\"]Show Answer[\/reveal-answer]\r\n[hidden-answer a=\"299465\"]\r\n\r\n1. An element is the basic chemical building block of matter; it is the simplest chemical substance.\r\n\r\n2. Elements vary from being a small percentage to more than 30% of the atoms around us.\r\n\r\n3. Chemical symbols are useful to concisely represent the elements present in a substance. The letters usually come from the name of the element.[\/hidden-answer]\r\n
                  \r\n\r\n \r\n
                  <\/div>\r\n \r\n
                  \r\n

                  <\/p>\r\n\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n<\/div>\r\n

                  \r\n
                  \r\n

                  Key Takeaways<\/h3>\r\n