We live at the bottom of the ocean of air that envelops our planet. The atmosphere, weighing down upon Earth’s surface under the force of gravity, exerts a pressure at sea level that scientists define as 1 bar (a term that comes from the same root as barometer, an instrument used to measure atmospheric pressure). A bar of pressure means that each square centimeter of Earth’s surface has a weight equivalent to 1.03 kilograms pressing down on it. Humans have evolved to live at this pressure; make the pressure a lot lower or higher and we do not function well.

The total mass of Earth’s atmosphere is about 5 × 10¹⁸ kilograms. This sounds like a large number, but it is only about a millionth of the total mass of Earth. The atmosphere represents a smaller fraction of Earth than the fraction of your mass represented by the hair on your head.

Structure of the Atmosphere

Figure 1. Structure of Earth’s Atmosphere: Height increases up the left side of the diagram, and the names of the different atmospheric layers are shown at the right. In the upper ionosphere, ultraviolet radiation from the Sun can strip electrons from their atoms, leaving the atmosphere ionized. The curving red line shows the temperature (see the scale on the x-axis).

The structure of the atmosphere is illustrated in Figure 1. Most of the atmosphere is concentrated near the surface of Earth, within about the bottom 10 kilometers where clouds form and airplanes fly. Within this region—called the troposphere—warm air, heated by the surface, rises and is replaced by descending currents of cooler air; this is an example of convection. This circulation generates clouds and wind. Within the troposphere, temperature decreases rapidly with increasing elevation to values near 50 °C below freezing at its upper boundary, where the stratosphere begins. Most of the stratosphere, which extends to about 50 kilometers above the surface, is cold and free of clouds.

Near the top of the stratosphere is a layer of ozone (O₃), a heavy form of oxygen with three atoms per molecule instead of the usual two. Because ozone is a good absorber of ultraviolet light, it protects the surface from some of the Sun’s dangerous ultraviolet radiation, making it possible for life to exist on Earth. The breakup of ozone adds heat to the stratosphere, reversing the decreasing temperature trend in the troposphere. Because ozone is essential to our survival, we reacted with justifiable concern to evidence that became clear in the 1980s that atmospheric ozone was being destroyed by human activities. By international agreement, the production of industrial chemicals that cause ozone depletion, called chlorofluorocarbons, or CFCs, has been phased out. As a result, ozone loss has stopped and the “ozone hole” over the Antarctic is shrinking gradually. This is an example of how concerted international action can help maintain the habitability of Earth.

At heights above 100 kilometers, the atmosphere is so thin that orbiting satellites can pass through it with very little friction. Many of the atoms are ionized by the loss of an electron, and this region is often called the ionosphere. At these elevations, individual atoms can occasionally escape completely from the gravitational field of Earth. There is a continuous, slow leaking of atmosphere—especially of lightweight atoms, which move faster than heavy ones. Earth’s atmosphere cannot, for example, hold on for long to hydrogen or helium, which escape into space. Earth is not the only planet to experience atmosphere leakage. Atmospheric leakage also created Mars’ thin atmosphere. Venus’ dry atmosphere evolved because its proximity to the Sun vaporized and dissociated any water, with the component gases lost to space.

Atmospheric Composition and Origin

At Earth’s surface, the atmosphere consists of 78% nitrogen (N₂), 21% oxygen (O₂), and 1% argon (Ar), with traces of water vapor (H₂O), carbon dioxide (CO₂), and other gases. Variable amounts of dust particles and water droplets are also found suspended in the air.

A complete census of Earth’s volatile materials, however, should look at more than the gas that is now present. Volatile materials are those that evaporate at a relatively low temperature. If Earth were just a little bit warmer, some materials that are now liquid or solid might become part of the atmosphere. Suppose, for example, that our planet were heated to above the boiling point of water (100 °C, or 373 K); that’s a large change for humans, but a small change compared to the range of possible temperatures in the universe. At 100 °C, the oceans would boil and the resulting water vapor would become a part of the atmosphere.

To estimate how much water vapor would be released, note that there is enough water to cover the entire Earth to a depth of about 300 meters. Because the pressure exerted by 10 meters of water is equal to about 1 bar, the average pressure at the ocean floor is about 300 bars. Water weighs the same whether in liquid or vapor form, so if the oceans boiled away, the atmospheric pressure of the water would still be 300 bars. Water would therefore greatly dominate Earth’s atmosphere, with nitrogen and oxygen reduced to the status of trace constituents.

On a warmer Earth, another source of additional atmosphere would be found in the sedimentary carbonate rocks of the crust. These minerals contain abundant carbon dioxide. If all these rocks were heated, they would release about 70 bars of CO₂, far more than the current CO₂ pressure of only 0.0005 bar. Thus, the atmosphere of a warm Earth would be dominated by water vapor and carbon dioxide, with a surface pressure nearing 400 bars.

Several lines of evidence show that the composition of Earth’s atmosphere has changed over our planet’s history. Scientists can infer the amount of atmospheric oxygen, for example, by studying the chemistry of minerals that formed at various times. We examine this issue in more detail later in this chapter.

Today we see that CO₂, H₂O, sulfur dioxide (SO₂), and other gases are released from deeper within Earth through the action of volcanoes. (For CO₂, the primary source today is the burning of fossil fuels, which releases far more CO₂ than that from volcanic eruptions.) Much of this apparently new gas, however, is recycled material that has been subducted through plate tectonics. But where did our planet’s original atmosphere come from?

Three possibilities exist for the original source of Earth’s atmosphere and oceans: (1) the atmosphere could have been formed with the rest of Earth as it accumulated from debris left over from the formation of the Sun; (2) it could have been released from the interior through volcanic activity, subsequent to the formation of Earth; or (3) it may have been derived from impacts by comets and asteroids from the outer parts of the solar system. Current evidence favors a combination of the interior and impact sources.

Weather and Climate

Figure 2. Storm from Space: This satellite image shows Hurricane Irene in 2011, shortly before the storm hit land in New York City. The combination of Earth’s tilted axis of rotation, moderately rapid rotation, and oceans of liquid water can lead to violent weather on our planet. (credit: NASA/NOAA GOES Project)

All planets with atmospheres have weather, which is the name we give to the circulation of the atmosphere. The energy that powers the weather is derived primarily from the sunlight that heats the surface. Both the rotation of the planet and slower seasonal changes cause variations in the amount of sunlight striking different parts of Earth. The atmosphere and oceans redistribute the heat from warmer to cooler areas. Weather on any planet represents the response of its atmosphere to changing inputs of energy from the Sun (see Figure 2 for a dramatic example).

Climate is a term used to refer to the effects of the atmosphere that last through decades and centuries. Changes in climate (as opposed to the random variations in weather from one year to the next) are often difficult to detect over short time periods, but as they accumulate, their effect can be devastating. One saying is that “Climate is what you expect, and weather is what you get.” Modern farming is especially sensitive to temperature and rainfall; for example, calculations indicate that a drop of only 2 °C throughout the growing season would cut the wheat production by half in Canada and the United States. At the other extreme, an increase of 2 °C in the average temperature of Earth would be enough to melt many glaciers, including much of the ice cover of Greenland, raising sea level by as much as 10 meters, flooding many coastal cities and ports, and putting small islands completely under water.

The best documented changes in Earth’s climate are the great ice ages, which have lowered the temperature of the Northern Hemisphere periodically over the past half million years or so (Figure 3). The last ice age, which ended about 14,000 years ago, lasted some 20,000 years. At its height, the ice was almost 2 kilometers thick over Boston and stretched as far south as New York City.

Figure 3. Ice Age: This computer-generated image shows the frozen areas of the Northern Hemisphere during past ice ages from the vantage point of looking down on the North Pole. The area in black indicates the most recent glaciation (coverage by glaciers), and the area in gray shows the maximum level of glaciation ever reached. (credit: modification of work by Hannes Grobe/AWI)

These ice ages were primarily the result of changes in the tilt of Earth’s rotational axis, produced by the gravitational effects of the other planets. We are less certain about evidence that at least once (and perhaps twice) about a billion years ago, the entire ocean froze over, a situation called snowball Earth.

The development and evolution of life on Earth has also produced changes in the composition and temperature of our planet’s atmosphere, as we shall see in the next section.

Glossary

bar: a force of 100,000 Newtons acting on a surface area of 1 square meter; the average pressure of Earth’s atmosphere at sea level is 1.013 bars

ozone: (O₃) a heavy molecule of oxygen that contains three atoms rather than the more normal two

stratosphere: the layer of Earth’s atmosphere above the troposphere and below the ionosphere

troposphere: the lowest level of Earth’s atmosphere, where most weather takes place